Today I cleaned the toilet using this recipe and all looks good! Loved the huge fizzing action mixing the two created in the bowl. The bowl came up white and sparkling as a result, looks the same as other products I've used so I'm happy. (Note: our toilet is kept fairly clean though so I didn't have any rings to get off etc so can't comment on how this works on that)
Baking Soda and Vinegar Cleaner
- 1Sprinkle a 1/4 cup of baking soda around the bowl of the toilet.
 - 2Pour 1 cup vinegar around the toilet bowl.
 - 3Scrub the toilet lightly to spread the cleaner around.
 - 4Allow the cleaner to sit for five minutes.
 - 5Scrub the toilet again.
 - 6Flush the toilet to rinse away the cleaner.
Source: http://www.ehow.com/how_7782001_homemade-toilet-cleaning-supplies.html#ixzz1LVD5GSVE 
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